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If you're talking about trying to scale up a photo, converting it to vector wouldn't be much help. That would work for a drawing, cartoon, etc., but you'd have a hard time making something "photorealistic" using filled shapes.
While there's really no way to upscale an image without losing some quality, you can achieve better results from taking small steps instead of one large one. Try an experiment: scale one copy of your image up by 100% (doubling it's size) and, with a second copy, scale it up by 10% several times until it's the same size then compare the two. You may find the second one to be a better one. You might also want to sharpen the image a little between steps, as necessary, to help keep the image from getting too blurry as you go.
Like I said, you're still going to lose quality either way, but a little experimenting goes a long way - you may even find a better solution and come back here to tell us all about it.
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